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The electronic properties of three porphyrin—bridge—anchor photosensitizers are reported with 1a , 1e , 3a and 3e or without 2a and 2e an intramolecular dipole in the bridge. The presence and orientation of the bridge dipole is hypothesized to influence the photovoltaic properties due to variations in the intrinsic dipole at the semiconductor—molecule interface. Electrochemical studies of the porphyrin—bridge—anchor dyes self-assembled on mesoporous nanoparticle ZrO 2 films, show that the presence or direction of the bridge dipole does not have an observable effect on the electronic properties of the porphyrin ring. Subsequent photovoltaic measurements of nanostructured TiO 2 semiconductor films in dye sensitized solar cells show a reduced photocurrent for photosensitizers 1a and 3a containing a bridge dipole. The article was received on 18 May , accepted on 15 Jun and first published on 16 Jun If you are not the author of this article and you wish to reproduce material from it in a third party non-RSC publication you must formally request permission using Copyright Clearance Center.
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Pic of naghma afghan sxy
Pic of naghma afghan sxy
Pic of naghma afghan sxy
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She and her ex-husband, Mangal, were a popular musical duo who dominated the Afghan music scene during the s and early s. Naghma sings mostly in Pashto but has also recorded in the Dari Persian language. Her music is popular in Afghanistan , Tajikistan and among Pashtuns in Pakistan. She is considered to be the greatest female artist in Afghanistan and continues to be the voice and face of Pashtun traditional music. The city of her birth cannot be verified.
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